UniSysCat: Publications

UniSysCat Publications

Electron microscopy of liquid–solid interfaces, E. Ortega, S. W. Chee in Encyclopedia of Solid-Liquid Interfaces (Hrsg.: Klaus Wandelt and Gianlorenzo Bussetti), Elsevier, 2024, 0–0, ISBN: 978-0-12-409547-2
Operando Insights into correlating CO coverage and Cu–Au alloying with the selectivity of Au NP-decorated Cu₂O nanocubes during the electrocatalytic CO₂ reduction, C. Rettenmaier, A. Herzog, D. Casari, M. Rüscher, H. S. Jeon, D. Kordus, M. Lopez Luna, S. Kühl, U. Hejral, E. M. Davis, S. W. Chee, J. Timoshenko, D. T. L. Alexander, A. Bergmann, B. Roldan Cuenya, EES Catalysis 2024, 2, 311–323, 10.1039/d3ey00162h
Reversible Structural Evolution of Metal‐Nitrogen‐Doped Carbon Catalysts During CO₂ Electroreduction: An Operando X‐ray Absorption Spectroscopy Study, D. Hursán, J. Timoshenko, E. Ortega, H. S. Jeon, M. Rüscher, A. Herzog, C. Rettenmaier, S. W. Chee, A. Martini, D. Koshy, B. Roldán Cuenya, Advanced Materials 2024, 36, 2307809–0, 10.1002/adma.202307809
Spectromicroscopic study of the transformation with low energy ions of a hematite thin film into a magnetite/hematite epitaxial bilayer, M. J. Prieto, L. de Souza Caldas, L. C. Tănase, T. Schmidt, O. Rodríguez de la Fuente, Ultramicroscopy 2024, 255, 113855–0, 10.1016/j.ultramic.2023.113855
Controlling the Activation at Ni −CO Moieties through Lewis Acid Interactions in the Second Coordination Sphere, S. Wolff, V. Pelmenschikov, R. Müller, M. Ertegi, B. Cula, M. Kaupp, C. Limberg, Chemistry – A European Journal 2024, 10.1002/chem.202303112
In situ/operando plug-flow fixed-bed cell for synchrotron PXRD and XAFS investigations at high temperature, pressure, controlled gas atmosphere and ultra-fast heating, B. Bischoff, M. F. Bekheet, E. Dal Molin, S. Praetz, B. Kanngießer, R. Schomäcker, M. Etter, H. S. Jeppesen, A. Tayal, A. Gurlo, A. Gili, Journal of Synchrotron Radiation 2024, 31, 77–84, 10.1107/S1600577523009591
A quantitative microscopic view on the gas‐phase‐dependent phase transformation from tetragonal to monoclinic ZrO, M. F. Bekheet, L. Schlicker, R. Popescu, W. Riedel, M. Grünbacher, S. Penner, A. Gurlo, Journal of the American Ceramic Society 2024, 10.1111/jace.19749
Enhanced Methanol Synthesis from CO₂ Hydrogenation Achieved by Tuning the Cu–ZnO Interaction in ZnO/Cu O Nanocube Catalysts Supported on ZrO₂ and SiO₂, D. Kordus, S. Widrinna, J. Timoshenko, M. Lopez Luna, C. Rettenmaier, S. W. Chee, E. Ortega, O. Karslioglu, S. Kühl, B. Roldan Cuenya, Journal of the American Chemical Society 2024, 146, 8677–8687, 10.1021/jacs.4c01077
Electrocatalytic Nitrate and Nitrite Reduction toward Ammonia Using Cu₂O Nanocubes: Active Species and Reaction Mechanisms, L. Bai, F. Franco, J. Timoshenko, C. Rettenmaier, F. Scholten, H. S. Jeon, A. Yoon, M. Rüscher, A. Herzog, F. T. Haase, S. Kühl, S. W. Chee, A. Bergmann, R. C. Beatriz, Journal of the American Chemical Society 2024, 10.1021/jacs.3c13288
Shape-Dependent CO₂ Hydrogenation to Methanol over Cu₂ O Nanocubes Supported on ZnO, D. Kordus, J. Jelic, M. Lopez Luna, N. J. Divins, J. Timoshenko, S. W. Chee, C. Rettenmaier, J. Kröhnert, S. Kühl, A. Trunschke, R. Schlögl, F. Studt, B. Roldan Cuenya, Journal of the American Chemical Society 2023, 145, 3016–3030, 10.1021/jacs.2c11540
Reduction of SF CF iridium catalysis: radical trifluoromethylation of aromatics, D. Herbstritt, T. Braun, Chemical Communications 2023, 10.1039/d3cc00495c
Catalytically Generated Meerwein’s Salt-Type Oxonium Ions for Friedel–Crafts C(sp2)–H Methylation with Methanol, T. He, H. F. T. Klare, M. Oestreich, Journal of the American Chemical Society 2023, 145, 3795–3801, 10.1021/jacs.2c13341
Influence of the Distance between two Catalysts for CO to Dimethyl Ether Tandem Reaction, M. Javed, G. Brösigke, R. Schomäcker, J. U. Repke, Chemical Engineering & Technology 2023, 10.1002/ceat.202200541
An Amorphous Teflate Doped Aluminium Chlorofluoride: A Solid Lewis‐Superacid for the Dehydrofluorination of Fluoroalkanes, M. Bui, K. F. Hoffmann, T. Braun, S. Riedel, C. Heinekamp, K. Scheurell, G. Scholz, T. M. Stawski, F. Emmerling, ChemCatChem 2023, 202300350–0, 10.1002/cctc.202300350
Bifunctional catalysts for the conversion of CO into value-added products – distance as a design parameter for new catalysts, M. A. Rudolph, P. Isbrücker, R. Schomäcker, Catalysis Science & Technology 2023, 13, 3469–3482, 10.1039/d3cy00194f
Cationic Copper Species Stabilized by Zinc during the Electrocatalytic Reduction of CO₂ Revealed by In Situ X‐Ray Spectroscopy, J. Velasco‐Vélez, J. Poon, D. Gao, C. Chuang, A. Bergmann, T. E. Jones, S. Haw, J. Chen, E. Carbonio, R. V. Mom, D. Ivanov, R. Arrigo, B. Roldan Cuenya, A. Knop‐Gericke, R. Schlögl, Advanced Sustainable Systems 2023, 7, 2200453–0, 10.1002/adsu.202200453
Assessment of the Degradation Mechanisms of Cu Electrodes during the CO₂ Reduction Reaction, R. V. Mom, L. E. Sandoval-Diaz, D. Gao, C. H. Chuang, E. A. Carbonio, T. E. Jones, R. Arrigo, D. Ivanov, M. Hävecker, B. Roldan Cuenya, R. Schlögl, T. Lunkenbein, A. Knop-Gericke, J. J. Velasco-Vélez, ACS Applied Materials & Interfaces 2023, 15, 30052–30059, 10.1021/acsami.2c23007
Unraveling surface structures of gallium promoted transition metal catalysts in CO₂ hydrogenation, S. W. Lee, M. L. Luna, N. Berdunov, W. Wan, S. Kunze, S. Shaikhutdinov, B. Roldan Cuenya, Nature Communications 2023, 14, 4649–0, 10.1038/s41467-023-40361-3
Preparation and stability of the hexagonal phase of samarium oxide on Ru(0001), E. Pożarowska, L. Pleines, M. Ewert, M. J. Prieto, L. C. Tănase, L. de Souza Caldas, A. Tiwari, T. Schmidt, J. Falta, E. Krasovskii, C. Morales, J. I. Flege, Ultramicroscopy 2023, 250, 113755–0, 10.1016/j.ultramic.2023.113755
Surface charge dynamics on air-exposed ferroelectric Pb(Zr,Ti)O₃(001) thin films, L. E. Abramiuc, L. C. Tănase, M. J. Prieto, L. de Souza Caldas, A. Tiwari, N. G. Apostol, M. A. Huşanu, C. F. Chirilă, L. Trupină, T. Schmidt, L. Pintilie, C. M. Teodorescu, Nanoscale 2023, 15, 13062–13075, 10.1039/d3nr02690f
Mechanochemical solid state synthesis of copper(I)/NHC complexes with K PO, I. Remy-Speckmann, B. M. Zimmermann, M. Gorai, M. Lerch, J. F. Teichert, Beilstein Journal of Organic Chemistry 2023, 19, 440–447, 10.3762/bjoc.19.34
Photoswitching neutral homoaromatic hydrocarbons, T. Tran Ngoc, N. Grabicki, E. Irran, O. Dumele, J. F. Teichert, Nature Chemistry 2023, 15, 377–385, 10.1038/s41557-022-01121-w
Is Micellar Catalysis Green Chemistry?, F. Fabris, M. Illner, J. U. Repke, A. Scarso, M. Schwarze, Molecules 2023, 28, 4809–0, 10.3390/molecules28124809
Coordinative Stabilization of Single Bismuth Sites in a Carbon–Nitrogen Matrix to Generate Atom‐Efficient Catalysts for Electrochemical Nitrate Reduction to Ammonia, W. Zhang, S. Zhan, J. Xiao, T. Petit, C. Schlesiger, M. Mellin, J. P. Hofmann, T. Heil, R. Müller, K. Leopold, M. Oschatz, Advanced Science 2023, 10.1002/advs.202302623
Role of Potassium in Electrocatalytic Water Oxidation Investigated in a Volume‐Active Cobalt Material at Neutral pH, S. Liu, S. Farhoosh, P. Beyer, S. Mebs, I. Zaharieva, M. Haumann, H. Dau, Advanced Sustainable Systems 2023, 7, 10.1002/adsu.202300008
Oxygen Evolution Reaction by Silicate-Stabilized Manganese Oxide, Z. Zand, M. R. Mohammadi, A. S. Sologubenko, S. Handschin, R. Bagheri, P. Chernev, Z. Song, H. Dau, M. M. Najafpour, ACS Applied Energy Materials 2023, 6, 1702–1713, 10.1021/acsaem.2c03587
Tuning electrocatalytic water oxidation by MnO through the incorporation of abundant metal cations, J. Melder, S. Mebs, F. Lessing, H. Dau, P. Kurz, Sustainable Energy & Fuels 2023, 7, 92–105, 10.1039/d2se01401g
Oxidation State Dependent Conjugation Controls Electrocatalytic Activity in a Two-Dimensional Di-Copper Metal–Organic Framework, A. M. Dominic, Z. Wang, A. Kuc, P. Petkov, K. H. Ly, T. L. H. Pham, M. Kutzschbach, Y. Cao, J. Bachmann, X. Feng, R. Dong, I. M. Weidinger, The Journal of Physical Chemistry C 2023, 127, 7299–7307, 10.1021/acs.jpcc.2c08819
Potential Induced Protonation of the Second Coordination Sphere in a Hangman-type Iron Porphyrin Complex Promotes HER: Insights via in Situ Raman Spectroelectrochemistry, A. R. Ramuglia, M. Göbel, V. Budhija, M. Werheid, K. H. Ly, M. Schwalbe, I. M. Weidinger, Inorganic Chemistry 2023, 62, 10232–10240, 10.1021/acs.inorgchem.3c00946
Silylium Ion Initiated Intramolecular Friedel–Crafts-Type Cyclization of 1,1-Difluoroalkenes with Subsequent Hydrodefluorination of C(sp3)–F Bonds, A. Roy, H. Gao, H. F. T. Klare, M. Oestreich, Synthesis 2023, 55, 1602–1612, 10.1055/a-2009-8114
Recent advances in low-valent silicon chemistry, A. Saddington, S. Yao, M. Driess in Advances in Inorganic Chemistry (Hrsg.: Academic Press), Elsevier, 2023, 0–0, ISBN: 0898-8838
Interaction of Gallium with a Copper Surface: Surface Alloying and Formation of Ordered Structures, S. W. Lee, A. Subramanian, F. B. Zamudio, J. Q. Zhong, S. M. Kozlov, S. Shaikhutdinov, B. Roldan Cuenya, The Journal of Physical Chemistry C 2023, 127, 20700–20709, 10.1021/acs.jpcc.3c05711
Arenium-ion-catalysed halodealkylation of fully alkylated silanes, T. He, H. F. T. Klare, M. Oestreich, Nature 2023, 623, 538–543, 10.1038/s41586-023-06646-9
Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions, P. W. Long, T. He, H. F. T. Klare, M. Oestreich, Synlett 2023, 10.1055/a-2188-1842
A Doubly Reduced Dipalladium Dibenzylideneacetone Complex, S. Paul, T. Lohmiller, J. Barrera, C. Herwig, B. Cula, A. Quensel, C. Limberg, Organometallics 2023, 42, 3434–3437, 10.1021/acs.organomet.3c00401
NMR spectroscopic investigations on the successive implementation of nickel and zinc ions to a NacNac‐dibenzofuran‐Br ligand precursor, K. B. Krause, B. Cula, A. Dallmann, C. Limberg, Zeitschrift für Anorganische und Allgemeine Chemie 2023, 649, 10.1002/zaac.202300178
Controlling the Coke Formation in Dehydrogenation of Propane by Adding Nickel to Supported Gallium Oxide, R. Baumgarten, P. Ingale, F. Ebert, A. Mazheika, E. Gioria, K. Trapp, K. D. Profita, R. Naumann d'Alnoncourt, M. Driess, F. Rosowski, ChemCatChem 2023, 10.1002/cctc.202301261
CuNi Nanoalloys with Tunable Composition and Oxygen Defects for the Enhancement of the Oxygen Evolution Reaction**, E. Gioria, S. Li, A. Mazheika, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, Angewandte Chemie 2023, 135, 10.1002/ange.202217888
Data-Centric Heterogeneous Catalysis: Identifying Rules and Materials Genes of Alkane Selective Oxidation, L. Foppa, F. Rüther, M. Geske, G. Koch, F. Girgsdies, P. Kube, S. J. Carey, M. Hävecker, O. Timpe, A. V. Tarasov, M. Scheffler, F. Rosowski, R. Schlögl, A. Trunschke, Journal of the American Chemical Society 2023, 145, 3427–3442, 10.1021/jacs.2c11117
Niobium Insertion into α -VOPO : Tuning the Catalytic Properties for Selective Oxidation, F. Rüther, R. Machado, E. Gioria, S. L. Kunz, K. Wittich, P. Löser, M. Geske, S. A. Schunk, R. Glaum, F. Rosowski, ACS Catalysis 2023, 13, 3295–3307, 10.1021/acscatal.2c06209
The Catalytic Function of Phosphorus Enriched on the Surface of Vanadium‐based Catalysts in Selective Oxidations, F. Rüther, R. Baumgarten, E. Gioria, K. Knemeyer, J. Xie, R. Kraehnert, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, ChemCatChem 2023, 15, 10.1002/cctc.202300839
Tuning catalysis by surface-deposition of elements on oxidation catalysts atomic layer deposition, F. Rüther, R. Baumgarten, F. Ebert, E. Gioria, R. Naumann d'Alnoncourt, A. Trunschke, F. Rosowski, Catalysis Science & Technology 2023, 13, 4117–4130, 10.1039/d2cy02184f
Bimetallic Carbonyl Complexes Based on Iridium and Rhodium: Useful Tools for Hydrodefluorination Reactions, K. Kretschmar, V. Pelmenschikov, M. Kaupp, T. Braun, P. Wittwer, S. Rachor, J. Cardozo, European Journal of Inorganic Chemistry 2023, 26, 10.1002/ejic.202300099
Core-Sheath Pt-CeO2/Mesoporous SiO2 Electrospun Nanofibers as Catalysts for the Reverse Water Gas Shift Reaction, A. Nejadsalim, N. Bashiri, H. R. Godini, R. L. Oliveira, A. Tufail Shah, M. F. Bekheet, A. Thomas, R. Schomäcker, A. Gurlo, O. Görke, Nanomaterials 2023, 13, 485–0, 10.3390/nano13030485
Hydrogenation of Carbon Dioxide to Dimethyl Ether on CuO–ZnO/ZSM-5 Catalysts: Comparison of Powder and Electrospun Structures, A. Nejadsalim, H. R. Godini, S. Ramesh Kumar, F. Gallucci, D. Kober, A. Gurlo, O. Görke, Materials 2023, 16, 7255–0, 10.3390/ma16237255
Efficient global sensitivity analysis of kinetic Monte Carlo simulations using Cramérs–von Mises distance, S. Dortaj, S. Matera, The Journal of Chemical Physics 2023, 159, 94110–1, 10.1063/5.0160873
Reduced Basis Approach for Convection-Diffusion Equations with Non-linear Boundary Reaction Conditions, S. Matera, C. Merdon, D. Runge in Finite Volumes for Complex Applications X—Volume 1, Elliptic and Parabolic Problems (Hrsg.: Franck, E., Fuhrmann, J., Michel-Dansac, V., Navoret, L.), Springer, 2023, 335–343, ISBN: 978-3-031-40864-9
Recent advances in low-valent silicon chemistry, A. Saddington, S. Yao, M. Driess in Adavances in Inorganic Chemistry (Hrsg.: Academic Press), Elsevier, 2023, 119–156, ISBN: 978-0-443-15944-2
New Avenues to Chemical Space for Energy Materials by the Molecular Precursor Approach, S. Ghosh, B. Dasgupta, C. Walter, P. W. Menezes, M. Driess, Small Science 2023, 3, 10.1002/smsc.202200115
A class of non-aromatic 1,3-disilapyrroles acting as stable organosilicon-based triplet diradicals, Y. Xiong, S. Dong, S. Yao, C. Lorent, K. B. Krause, G. Vijaykumar, J. Zhu, C. Limberg, M. Driess, Nature Synthesis 2023, 2, 678–687, 10.1038/s44160-023-00279-6
Chelating Bis-silylenes As Powerful Ligands To Enable Unusual Low-Valent Main-Group Element Functions, S. Yao, A. Saddington, Y. Xiong, M. Driess, Accounts of Chemical Research 2023, 56, 475–488, 10.1021/acs.accounts.2c00763
Boosting the performance of Ni/Al O for the reverse water gas shift reaction through formation of CuNi nanoalloys, E. Gioria, P. Ingale, F. Pohl, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, Catalysis Science & Technology 2022, 12, 474–487, 10.1039/D1CY01585K
Tracking the phase changes in micelle-based NiGa nanocatalysts for methanol synthesis under activation and working conditions, U. Hejral, J. Timoshenko, D. Kordus, M. Lopez Luna, N. J. Divins, S. Widrinna, I. Zegkinoglou, L. Pielsticker, H. Mistry, J. A. Boscoboinik, S. Kuehl, B. Roldan Cuenya, Journal of Catalysis 2022, 405, 183–198, 10.1016/j.jcat.2021.11.024
Property-reactivity relations of N-doped PEM fuel cell cathode catalyst supports, S. Ott, F. Du, M. Lopez Luna, T. A. Dao, S. Selve, B. Roldan Cuenya, A. Orfanidi, P. Strasser, Applied Catalysis B: Environmental 2022, 306, 121118–0, 10.1016/j.apcatb.2022.121118
Cu /Cu decorated N-doped carbonaceous electrocatalysts for the oxygen reduction reaction, J. Kossmann, M. L. Ortíz Sánchez-Manjavacas, H. Zschiesche, N. V. Tarakina, M. Antonietti, J. Albero, N. López-Salas, Journal of Materials Chemistry A 2022, 10.1039/d1ta09459a
A Look at Real‐World Transition‐Metal Thermochemistry and Kinetics with Local Hybrid Functionals, R. Grotjahn, M. Kaupp, Israel Journal of Chemistry 2022, 10.1002/ijch.202200021
Intermolecular Carbosilylation of α‐Olefins with C(sp )−C(sp) Bond Formation Involving Silylium‐Ion Regeneration, T. He, Z. Qu, H. F. T. Klare, S. Grimme, M. Oestreich, Angewandte Chemie International Edition 2022, 61, 202203347–202203347, 10.1002/anie.202203347
Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis, T. He, H. F. T. Klare, M. Oestreich, Journal of the American Chemical Society 2022, 144, 4734–4738, 10.1021/jacs.2c00080
Spectroscopic Properties of a Biologically Relevant [Fe2(μ‐O)2] Diamond Core Motif with a Short Iron‐Iron distance, D. Kass, S. Yao, K. Krause, T. Corona, L. Richter, T. Braun, S. Mebs, M. Haumann, H. Dau, T. Lohmiller, C. Limberg, M. Drieß, K. Ray, Angewandte Chemie 2022, 10.1002/ange.202209437
Programmable Photocatalytic Activity of Multicomponent Covalent Organic Frameworks Used as Metallaphotocatalysts, M. Traxler, S. Reischauer, S. Vogl, J. Roeser, J. Rabeah, C. Penschke, P. Saalfrank, B. Pieber, A. Thomas, Chemistry – A European Journal 2022, 10.1002/chem.202202967
Covalent Organic Framework (COF) Derived Ni‐N‐C Catalysts for Electrochemical CO Reduction: Unraveling Fundamental Kinetic and Structural Parameters of the Active Sites, C. Li, W. Ju, S. Vijay, J. Timoshenko, K. Mou, D. A. Cullen, J. Yang, X. Wang, P. Pachfule, S. Brückner, H. S. Jeon, F. T. Haase, S. Tsang, C. Rettenmaier, K. Chan, B. Roldan Cuenya, A. Thomas, P. Strasser, Angewandte Chemie International Edition 2022, 61, 202114707–0, 10.1002/anie.202114707
Steering the structure and selectivity of CO₂ electroreduction catalysts by potential pulses, J. Timoshenko, A. Bergmann, C. Rettenmaier, A. Herzog, R. M. Arán-Ais, H. S. Jeon, F. T. Haase, U. Hejral, P. Grosse, S. Kühl, E. M. Davis, J. Tian, O. Magnussen, B. Roldan Cuenya, Nature Catalysis 2022, 5, 259–267, 10.1038/s41929-022-00760-z
Tracking heterogeneous structural motifs and the redox behaviour of copper–zinc nanocatalysts for the electrocatalytic CO reduction using operando time resolved spectroscopy and machine learning, M. Rüscher, A. Herzog, J. Timoshenko, H. S. Jeon, W. Frandsen, S. Kühl, B. Roldan Cuenya, Catalysis Science & Technology 2022, 12, 3028–3043, 10.1039/D2CY00227B
Size effects and active state formation of cobalt oxide nanoparticles during the oxygen evolution reaction, F. T. Haase, A. Bergmann, T. E. Jones, J. Timoshenko, A. Herzog, H. S. Jeon, C. Rettenmaier, B. Roldan Cuenya, Nature Energy 2022, 7, 765–773, 10.1038/s41560-022-01083-w
Plasma Functionalization of Silica Bilayer Polymorphs, M. J. Prieto, T. Mullan, W. Wan, L. C. Tănase, L. de Souza Caldas, S. Shaikhutdinov, J. Sauer, D. Usvyat, T. Schmidt, B. Roldan Cuenya, ACS Applied Materials & Interfaces 2022, 14, 48609–48618, 10.1021/acsami.2c11491
Adatom Bonding Sites in a Nickel‐Fe O (001) Single‐Atom Model Catalyst and O Reactivity Unveiled by Surface Action Spectroscopy with Infrared Free‐Electron Laser Light, Y. Liu, Z. Han, S. Gewinner, W. Schöllkopf, S. V. Levchenko, H. Kuhlenbeck, B. Roldan Cuenya, Angewandte Chemie International Edition 2022, 61, 202202561–0, 10.1002/anie.202202561
Highly Stable and Reactive Platinum Single Atoms on Oxygen Plasma‐Functionalized CeO₂ Surfaces: Nanostructuring and Peroxo Effects, W. Wan, J. Geiger, N. Berdunov, M. Lopez Luna, S. W. Chee, N. Daelman, N. López, S. Shaikhutdinov, B. Roldan Cuenya, Angewandte Chemie International Edition 2022, 61, 202112640–0, 10.1002/anie.202112640
The 2022 solar fuels roadmap, G. Segev, J. Kibsgaard, C. Hahn, Z. J. Xu, W. H. (. Cheng, T. G. Deutsch, C. Xiang, J. Z. Zhang, L. Hammarström, D. G. Nocera, A. Z. Weber, P. Agbo, T. Hisatomi, F. E. Osterloh, K. Domen, F. F. Abdi, S. Haussener, D. J. Miller, S. Ardo, P. C. McIntyre, T. Hannappel, S. Hu, H. Atwater, J. M. Gregoire, M. Z. Ertem, I. D. Sharp, K. S. Choi, J. S. Lee, O. Ishitani, J. W. Ager, R. R. Prabhakar, A. T. Bell, S. W. Boettcher, K. Vincent, K. Takanabe, V. Artero, R. Napier, B. Roldan Cuenya, M. T. M. Koper, R. Van De Krol, F. Houle, Journal of Physics D: Applied Physics 2022, 55, 323003–0, 10.1088/1361-6463/ac6f97
Dehydrofluorination reactions at Lewis acidic ACF in the presence of HSnBu3, X. Pan, M. Talavera, T. Braun, Journal of Fluorine Chemistry 2022, 263, 110046–0, 10.1016/j.jfluchem.2022.110046
Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion, H. Gao, R. Müller, E. Irran, H. F. T. Klare, M. Kaupp, M. Oestreich, Chemistry – A European Journal 2022, 28, 202104464–202104464, 10.1002/chem.202104464
Electrochemical Generation of Catalytically Active Edge Sites in C N‐Type Carbon Materials for Artificial Nitrogen Fixation, W. Zhang, S. Zhan, Q. Qin, T. Heil, X. Liu, J. Hwang, T. H. Ferber, J. P. Hofmann, M. Oschatz, Small 2022, 18, 10.1002/smll.202204116
Comparative Spectroscopic Study Revealing Why the CO Electroreduction Selectivity Switches from CO to HCOO at Cu–Sn- and Cu–In-Based Catalysts, G. A. El-Nagar, F. Yang, S. Stojkovikj, S. Mebs, S. Gupta, I. Y. Ahmet, H. Dau, M. T. Mayer, ACS Catalysis 2022, 12, 15576–15589, 10.1021/acscatal.2c04419
Electrocatalytic Water Oxidation at Neutral pH–Deciphering the Rate Constraints for an Amorphous Cobalt‐Phosphate Catalyst System, S. Liu, I. Zaharieva, L. D'Amario, S. Mebs, P. Kubella, F. Yang, P. Beyer, M. Haumann, H. Dau, Advanced Energy Materials 2022, 12, 10.1002/aenm.202202914
Quantification and Tuning of Surface Oxygen Vacancies for the Hydrogenation of CO on Indium Oxide Catalysts, R. Baumgarten, R. Naumann d'Alnoncourt, S. Lohr, E. Gioria, E. Frei, E. Fako, S. De, C. Boscagli, M. Drieß, S. Schunk, F. Rosowski, Chemie Ingenieur Technik 2022, 94, 1765–1775, 10.1002/cite.202200085
The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero‐Valent Lead Complex (“Plumbylone”), J. Xu, S. Pan, S. Yao, G. Frenking, M. Driess, Angewandte Chemie International Edition 2022, 61, 10.1002/anie.202209442
Synthesis of High Surface Area—Group 13—Metal Oxides via Atomic Layer Deposition on Mesoporous Silica, R. Baumgarten, P. Ingale, K. Knemeyer, R. Naumann d’Alnoncourt, M. Driess, F. Rosowski, Nanomaterials 2022, 12, 1458–0, 10.3390/nano12091458
A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d -Mn(CO) radical, S. Kalra, D. Pividori, D. Fehn, C. Dai, S. Dong, S. Yao, J. Zhu, K. Meyer, M. Driess, Chemical Science 2022, 13, 8634–8641, 10.1039/D2SC03352F
Use of Cellulose for the Production of Photocatalytic Films for Hydrogen Evolution Along the Lines of Paper Production, M. Schwarze, T. A. Thiel, M. Tasbihi, M. Schroeter, P. W. Menezes, C. Walter, M. Driess, R. Schomäcker, Energy Technology 2022, 10, 10.1002/ente.202100525
Stable Isotopomers of Inositol Uncover a Complex MINPP1-Dependent Inositol Phosphate Network, M. Nguyen Trung, S. Kieninger, Z. Fandi, D. Qiu, G. Liu, N. K. Mehendale, A. Saiardi, H. Jessen, B. Keller, D. Fiedler, ACS Central Science 2022, 8, 1683–1694, 10.1021/acscentsci.2c01032
Silica‐supported Catalyst System Rh−Mn−Ir−Li−Ti in Syngas to Ethanol Reaction: Reactivity Trends and Performance Optimization, M. Khatamirad, M. Konrad, M. Gentzen, C. Almer, C. Boscagli, N. Bottke, M. Geske, F. Rosowski, R. Kraehnert, ChemCatChem 2022, 15, 10.1002/cctc.202201104
The closer the better? Theoretical assessment of the impact of catalytic site separation for bifunctional core–shell catalyst particles, G. Brösigke, J. U. Repke, R. Schomäcker, S. Matera, Chemical Engineering Journal 2022, 446, 136891–0, 10.1016/j.cej.2022.136891
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Structural Evolution of Ga–Cu Model Catalysts for CO₂ Hydrogenation Reactions, J. Q. Zhong, S. Shaikhutdinov, B. Roldan Cuenya, The Journal of Physical Chemistry C 2021, 125, 1361–1367, 10.1021/acs.jpcc.0c09382
Potential‐Dependent Morphology of Copper Catalysts During CO₂ Electroreduction Revealed by In Situ Atomic Force Microscopy, G. H. Simon, C. S. Kley, B. Roldan Cuenya, Angewandte Chemie International Edition 2021, 60, 2561–2568, 10.1002/anie.202010449
Design of an active and stable catalyst for dry reforming of methane via molecular layer deposition, P. Ingale, C. Guan, R. Kraehnert, R. Naumann d’Alnoncourt, A. Thomas, F. Rosowski, Catalysis Today 2021, 362, 47–54, 10.1016/j.cattod.2020.04.050
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Cover Feature: An Iron Porphyrin Complex with Pendant Pyridine Substituents Facilitates Electrocatalytic CO2 Reduction via Second Coordination Sphere Effects, A. R. Ramuglia, V. Budhija, K. H. Ly, M. Marquardt, M. Schwalbe, I. M. Weidinger, ChemCatChem 2021, 13, 3934–3944, 10.1002/cctc.202101193
Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers, R. Giereth, M. Obermeier, L. Forschner, M. Karnahl, M. Schwalbe, S. Tschierlei, ChemPhotoChem 2021, 5, 644–653, 10.1002/cptc.202100034
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Surface site density and utilization of platinum group metal (PGM)-free Fe–NC and FeNi–NC electrocatalysts for the oxygen reduction reaction, F. Luo, S. Wagner, I. Onishi, S. Selve, S. Li, W. Ju, H. Wang, J. Steinberg, A. Thomas, U. I. Kramm, P. Strasser, Chemical Science 2021, 12, 384–396, 10.1039/D0SC03280H
Design of PtZn nanoalloy catalysts for propane dehydrogenation through interface tailoring atomic layer deposition, P. Ingale, K. Knemeyer, P. Preikschas, M. Ye, M. Geske, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, Catalysis Science & Technology 2021, 11, 484–493, 10.1039/D0CY01528H
Formation, dynamics, and long-term stability of Mn- and Fe-promoted Rh/SiO catalysts in CO hydrogenation, P. Preikschas, J. Bauer, K. Knemeyer, R. Naumann d'Alnoncourt, R. Kraehnert, F. Rosowski, Catalysis Science & Technology 2021, 11, 5802–5815, 10.1039/d1cy00421b
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Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms, S. Yao, Y. Xiong, A. Saddington, M. Driess, Chemical Communications 2021, 57, 10139–10153, 10.1039/D1CC04100B
Unraveling Property‐Performance Relationships by Surface Tailoring of Oxidation Catalysts ALD, K. Knemeyer, J. D. Epping, F. Rüther, C. Schulz, B. Frank, P. Müller, R. N. d'Alnoncourt, M. Driess, F. Rosowski, ChemCatChem 2021, 13, 4201–4209, 10.1002/cctc.202100866
Distinctly different reactivity of bis(silylenyl)- phosphanyl-silylenyl-substituted -dicarborane towards O , N O and CO, Y. Xiong, S. Yao, A. Ruzicka, M. Driess, Chemical Communications 2021, 57, 5965–5968, 10.1039/D1CC01939B
Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand, S. Yao, A. Kostenko, Y. Xiong, C. Lorent, A. Ruzicka, M. Driess, Angewandte Chemie International Edition 2021, 60, 14864–14868, 10.1002/anie.202103769
New Types of Ge and Ge Assemblies Stabilized by a Carbanionic Dicarborandiyl-Silylene Ligand, Y. Xiong, D. Chen, S. Yao, J. Zhu, A. Ruzicka, M. Driess, Journal of the American Chemical Society 2021, 143, 6229–6237, 10.1021/jacs.1c01722
Well-Defined, Silica-Supported Homobimetallic Nickel Hydride Hydrogenation Catalyst, F. Czerny, K. Searles, P. Šot, J. F. Teichert, P. W. Menezes, C. Copéret, M. Driess, Inorganic Chemistry 2021, 60, 5483–5487, 10.1021/acs.inorgchem.0c03188
Tuning the Rh–FeO Interface in Ethanol Synthesis through Formation Phase Studies at High Pressures of Synthesis Gas, P. Preikschas, M. Plodinec, J. Bauer, R. Kraehnert, R. Naumann d’Alnoncourt, R. Schlögl, M. Driess, F. Rosowski, ACS Catalysis 2021, 11, 4047–4060, 10.1021/acscatal.0c05365
Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst, M. P. Lücke, S. Yao, M. Driess, Chemical Science 2021, 12, 2909–2915, 10.1039/D0SC06471H
Crystallographic Orientation Dependence of Surface Segregation and Alloying on PdCu Catalysts for CO₂ Hydrogenation, L. Pielsticker, I. Zegkinoglou, Z. K. Han, J. J. Navarro, S. Kunze, O. Karslıoğlu, S. V. Levchenko, B. Roldan Cuenya, The Journal of Physical Chemistry Letters 2021, 12, 2570–2575, 10.1021/acs.jpclett.1c00179
Low-Temperature Growth of Graphene on a Semiconductor, H. I. Røst, R. K. Chellappan, F. S. Strand, A. Grubišić-Čabo, B. P. Reed, M. J. Prieto, L. C. Tǎnase, L. de Souza Caldas, T. Wongpinij, C. Euaruksakul, T. Schmidt, A. Tadich, B. C. C. Cowie, Z. Li, S. P. Cooil, J. W. Wells, The Journal of Physical Chemistry C 2021, 125, 4243–4252, 10.1021/acs.jpcc.0c10870
Operando Investigation of Ag‐Decorated Cu₂O Nanocube Catalysts with Enhanced CO₂ Electroreduction toward Liquid Products, A. Herzog, A. Bergmann, H. S. Jeon, J. Timoshenko, S. Kühl, C. Rettenmaier, M. Lopez Luna, F. T. Haase, B. Roldan Cuenya, Angewandte Chemie International Edition 2021, 60, 7426–7435, 10.1002/anie.202017070
In situ and operando electron microscopy in heterogeneous catalysis—insights into multi-scale chemical dynamics, S. W. Chee, T. Lunkenbein, R. Schlögl, B. Roldan Cuenya, Journal of Physics: Condensed Matter 2021, 33, 153001–0, 10.1088/1361-648X/abddfd
Operando high-pressure investigation of size-controlled CuZn catalysts for the methanol synthesis reaction, N. J. Divins, D. Kordus, J. Timoshenko, I. Sinev, I. Zegkinoglou, A. Bergmann, S. W. Chee, S. Widrinna, O. Karslıoğlu, H. Mistry, M. Lopez Luna, J. Q. Zhong, A. S. Hoffman, A. Boubnov, J. A. Boscoboinik, M. Heggen, R. E. Dunin-Borkowski, S. R. Bare, B. Roldan Cuenya, Nature Communications 2021, 12, 1435–0, 10.1038/s41467-021-21604-7
Selectivity Control of Cu Nanocrystals in a Gas-Fed Flow Cell through CO₂ Pulsed Electroreduction, H. S. Jeon, J. Timoshenko, C. Rettenmaier, A. Herzog, A. Yoon, S. W. Chee, S. Oener, U. Hejral, F. T. Haase, B. Roldan Cuenya, Journal of the American Chemical Society 2021, 143, 7578–7587, 10.1021/jacs.1c03443
Role of the Oxide Support on the Structural and Chemical Evolution of Fe Catalysts during the Hydrogenation of CO₂, M. Lopez Luna, J. Timoshenko, D. Kordus, C. Rettenmaier, S. W. Chee, A. S. Hoffman, S. R. Bare, S. Shaikhutdinov, B. Roldan Cuenya, ACS Catalysis 2021, 11, 6175–6185, 10.1021/acscatal.1c01549
Revealing the CO Coverage-Driven C–C Coupling Mechanism for Electrochemical CO₂ Reduction on Cu₂O Nanocubes Raman Spectroscopy, C. Zhan, F. Dattila, C. Rettenmaier, A. Bergmann, S. Kühl, R. García-Muelas, N. López, B. Roldan Cuenya, ACS Catalysis 2021, 11, 7694–7701, 10.1021/acscatal.1c01478
A Simplified Method for Patterning Graphene on Dielectric Layers, H. I. Røst, B. P. Reed, F. S. Strand, J. A. Durk, D. A. Evans, A. Grubišić-Čabo, G. Wan, M. Cattelan, M. J. Prieto, D. M. Gottlob, L. C. Tănase, L. de Souza Caldas, T. Schmidt, A. Tadich, B. C. C. Cowie, R. K. Chellappan, J. W. Wells, S. P. Cooil, ACS Applied Materials & Interfaces 2021, 13, 37510–37516, 10.1021/acsami.1c09987
Identifying Structure–Selectivity Correlations in the Electrochemical Reduction of CO₂: A Comparison of Well‐Ordered Atomically Clean and Chemically Etched Copper Single‐Crystal Surfaces, F. Scholten, K. C. Nguyen, J. P. Bruce, M. Heyde, B. Roldan Cuenya, Angewandte Chemie International Edition 2021, 60, 19169–19175, 10.1002/anie.202103102
Plasma-assisted oxidation of Cu(100) and Cu(111), S. Kunze, L. C. Tănase, M. J. Prieto, P. Grosse, F. Scholten, L. de Souza Caldas, D. van Vörden, T. Schmidt, B. Roldan Cuenya, Chemical Science 2021, 12, 14241–14253, 10.1039/D1SC04861A
Dynamic transformation of cubic copper catalysts during CO₂ electroreduction and its impact on catalytic selectivity, P. Grosse, A. Yoon, C. Rettenmaier, A. Herzog, S. W. Chee, B. Roldan Cuenya, Nature Communications 2021, 12, 6736–0, 10.1038/s41467-021-26743-5
Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO, P. Zimmermann, A. F. R. Kilpatrick, D. Ar, S. Demeshko, B. Cula, C. Limberg, Chemical Communications 2021, 57, 875–878, 10.1039/D0CC06983C
Binding of a TlCl Entity by a Tetragold Tetramercaptothiacalixarene Metalloligand via Metallophilic Interactions, N. Frank, I. Pryjomska‐Ray, L. Grubert, S. Hecht, D. Usvyat, C. Limberg, Chemistry – A European Journal 2021, 27, 8344–8349, 10.1002/chem.202100298
Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron‐Deficient Platinum Single Atoms, K. Liu, B. Badamdorj, F. Yang, M. J. Janik, M. Antonietti, Angewandte Chemie International Edition 2021, 60, 24220–24226, 10.1002/anie.202109689
Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution, X. Lin, S. N. Zhang, D. Xu, J. J. Zhang, Y. X. Lin, G. Y. Zhai, H. Su, Z. H. Xue, X. Liu, M. Antonietti, J. S. Chen, X. H. Li, Nature Communications 2021, 12, 10.1038/s41467-021-24203-8
All-organic Z-scheme photoreduction of CO2 with water as the donor of electrons and protons, S. Mazzanti, S. Cao, K. ten Brummelhuis, A. Völkel, J. Khamrai, D. I. Sharapa, S. Youk, T. Heil, N. V. Tarakina, V. Strauss, I. Ghosh, B. König, M. Oschatz, M. Antonietti, A. Savateev, Applied Catalysis B: Environmental 2021, 285, 119773–0, 10.1016/j.apcatb.2020.119773
Acetic Anhydride Polymerization as a Pathway to Functional Porous Organic Polymers and Their Application in Acid–Base Catalysis, S. Rat, A. Chavez-Sanchez, M. Jerigová, D. Cruz, M. Antonietti, ACS Applied Polymer Materials 2021, 3, 2588–2597, 10.1021/acsapm.1c00202
Ceramic boron carbonitrides for unlocking organic halides with visible light, T. Yuan, M. Zheng, M. Antonietti, X. Wang, Chemical Science 2021, 12, 6323–6332, 10.1039/d1sc01028j
Mizoroki–Heck type reactions and synthesis of 1,4-dicarbonyl compounds by heterogeneous organic semiconductor photocatalysis, J. Khamrai, S. Das, A. Savateev, M. Antonietti, B. König, Green Chemistry 2021, 23, 2017–2024, 10.1039/d0gc03792c
Silylium-Ion Regeneration by Protodesilylation Enables Friedel–Crafts Alkylation with Less Isomerization and No Defunctionalization, T. He, H. F. T. Klare, M. Oestreich, ACS Catalysis 2021, 11, 12186–12193, 10.1021/acscatal.1c03602
The Power of the Proton: From Superacidic Media to Superelectrophile Catalysis, H. F. T. Klare, M. Oestreich, Journal of the American Chemical Society 2021, 143, 15490–15507, 10.1021/jacs.1c07614
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Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes, T. He, G. Wang, P. W. Long, S. Kemper, E. Irran, H. F. T. Klare, M. Oestreich, Chemical Science 2021, 12, 569–575, 10.1039/D0SC05553K
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Evolving Highly Active Oxidic Iron(III) Phase from Corrosion of Intermetallic Iron Silicide to Master Efficient Electrocatalytic Water Oxidation and Selective Oxygenation of 5‐Hydroxymethylfurfural, J. N. Hausmann, R. Beltrán‐Suito, S. Mebs, V. Hlukhyy, T. F. Fässler, H. Dau, M. Driess, P. W. Menezes, Advanced Materials 2021, 33, 1–9, 10.1002/adma.202008823
Deoxygenation of Nitrous Oxide and Nitro Compounds Using Bis(N‐Heterocyclic Silylene)Amido Iron Complexes as Catalysts, X. Chen, H. Wang, S. Du, M. Driess, Z. Mo, Angewandte Chemie International Edition 2021, 61, 10.1002/anie.202114598
A Genuine Stannylone with a Monoatomic Two‐Coordinate Tin(0) Atom Supported by a Bis(silylene) Ligand, J. Xu, C. Dai, S. Yao, J. Zhu, M. Driess, Angewandte Chemie International Edition 2021, 61, 10.1002/anie.202114073
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Revisiting the Intriguing Electronic Features of the BeOBeC Carbyne and Some Isomers: A Quantum‐Chemical Assessment, J. Li, C. Geng, T. Weiske, M. Zhou, J. Li, H. Schwarz, Angewandte Chemie International Edition 2020, 10.1002/anie.202007990
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A synthetic manganese–calcium cluster similar to the catalyst of Photosystem II: challenges for biomimetic water oxidation, Y. Mousazade, M. R. Mohammadi, R. Bagheri, R. Bikas, P. Chernev, Z. Song, T. Lis, M. Siczek, N. Noshiranzadeh, S. Mebs, H. Dau, I. Zaharieva, M. M. Najafpour, Dalton Transactions 2020, 49, 5597–5605, 10.1039/d0dt00536c
Exploring the Limits of Self-Repair in Cobalt Oxide Films for Electrocatalytic Water Oxidation, M. R. Mohammadi, S. Loos, P. Chernev, C. Pasquini, I. Zaharieva, D. González-Flores, P. Kubella, K. Klingan, R. D. L. Smith, H. Dau, ACS Catalysis 2020, 10, 7990–7999, 10.1021/acscatal.0c01944
Electrocatalytic CO Reduction on CuO Nanocubes: Tracking the Evolution of Chemical State, Geometric Structure, and Catalytic Selectivity using Operando Spectroscopy, T. Möller, F. Scholten, T. N. Thanh, I. Sinev, J. Timoshenko, X. Wang, Z. Jovanov, M. Gliech, B. Roldan Cuenya, A. S. Varela, P. Strasser, Angewandte Chemie 2020, 10.1002/ange.202007136
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Influence of Local Environments in Pores of Different Size on the Catalytic Liquid-Phase Oxidation of -Glucose by Au Nanoparticles Supported on Nanoporous Carbon, M. Perovic, N. V. Tarakina, J. P. Hofmann, M. Oschatz, ACS Applied Nano Materials 2020, 3, 7695–7703, 10.1021/acsanm.0c01299
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On the Crucial Role of Isolated Electronic States in the Thermal Reaction of ReC with Dihydrogen, J. Li, C. Geng, T. Weiske, H. Schwarz, Angewandte Chemie International Edition 2020, 59, 9370–9376, 10.1002/anie.202001599
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Transition metal-based catalysts for the electrochemical CO₂ reduction: from atoms and molecules to nanostructured materials, F. Franco, C. Rettenmaier, H. S. Jeon, B. Roldan Cuenya, Chemical Society Reviews 2020, 49, 6884–6946, 10.1039/D0CS00835D
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Operando Insight into the Correlation between the Structure and Composition of CuZn Nanoparticles and Their Selectivity for the Electrochemical CO Reduction, H. S. Jeon, J. Timoshenko, F. Scholten, I. Sinev, A. Herzog, F. T. Haase, B. Roldan Cuenya, Journal of the American Chemical Society 2019, 141, 19879–19887, 10.1021/jacs.9b10709
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