Publications 2019

  • Stereochemical Elucidation of Natural Products from Residual Chemical Shift Anisotropies in a Liquid Crystalline Phase, X. L. Li, L. P. Chi, A. Navarro-Vázquez, S. Hwang, P. Schmieder, X. M. Li, X. Li, S. Q. Yang, X. Lei, B. G. Wang, H. Sun, Journal of the American Chemical Society 2019, 142, 2301–2309, 10.1021/jacs.9b10961
  • Proton Transfer Pathways between Active Sites and Proximal Clusters in the Membrane-Bound [NiFe] Hydrogenase, D. Tombolelli, M. A. Mroginski, The Journal of Physical Chemistry B 2019, 123, 3409–3420, 10.1021/acs.jpcb.9b00617
  • Photocycle Dynamics of the Archaerhodopsin 3 Based Fluorescent Voltage Sensor QuasAr1, A. Penzkofer, A. Silapetere, P. Hegemann, International Journal of Molecular Sciences 2019, 21, 160–0, 10.3390/ijms21010160
  • Absorption and Emission Spectroscopic Investigation of the Thermal Dynamics of the Archaerhodopsin 3 Based Fluorescent Voltage Sensor QuasAr1, Penzkofer, Silapetere, Hegemann, International Journal of Molecular Sciences 2019, 20, 4086–0, 10.3390/ijms20174086
  • Unifying photocycle model for light adaptation and temporal evolution of cation conductance in channelrhodopsin-2, J. Kuhne, J. Vierock, S. A. Tennigkeit, M. A. Dreier, J. Wietek, D. Petersen, K. Gavriljuk, S. F. El-Mashtoly, P. Hegemann, K. Gerwert, Proceedings of the National Academy of Sciences 2019, 116, 9380–9389, 10.1073/pnas.1818707116
  • Tracking Pore Hydration in Channelrhodopsin by Site-Directed Infrared-Active Azido Probes, B. S. Krause, J. C. D. Kaufmann, J. Kuhne, J. Vierock, T. Huber, T. P. Sakmar, K. Gerwert, F. J. Bartl, P. Hegemann, Biochemistry 2019, 58, 1275–1286, 10.1021/acs.biochem.8b01211
  • Engineered Passive Potassium Conductance in the KR2 Sodium Pump, A. Vogt, A. Silapetere, C. Grimm, F. Heiser, M. Ancina Möller, P. Hegemann, Biophysical Journal 2019, 116, 1941–1951, 10.1016/j.bpj.2019.04.001
  • MerMAIDs: a family of metagenomically discovered marine anion-conducting and intensely desensitizing channelrhodopsins, J. Oppermann, P. Fischer, A. Silapetere, B. Liepe, S. Rodriguez-Rozada, J. Flores-Uribe, E. Peter, A. Keidel, J. Vierock, J. Kaufmann, M. Broser, M. Luck, F. Bartl, P. Hildebrandt, J. S. Wiegert, O. Béjà, P. Hegemann, J. Wietek, Nature Communications 2019, 10, 10.1038/s41467-019-11322-6
  • Red, Orange, Green: Light- and Temperature-Dependent Color Tuning in a Cyanobacteriochrome, D. Buhrke, G. Battocchio, S. Wilkening, M. Blain-Hartung, T. Baumann, F. J. Schmitt, T. Friedrich, M. A. Mroginski, P. Hildebrandt, Biochemistry 2019, 59, 509–519, 10.1021/acs.biochem.9b00931
  • Probing Structure and Reaction Dynamics of Proteins Using Time-Resolved Resonance Raman Spectroscopy, D. Buhrke, P. Hildebrandt, Chemical Reviews 2019, 120, 3577–3630, 10.1021/acs.chemrev.9b00429
  • Host–Guest Chemistry Meets Electrocatalysis: Cucurbit[6]uril on a Au Surface as a Hybrid System in CO Reduction, A. Wagner, K. H. Ly, N. Heidary, I. Szabó, T. Földes, K. I. Assaf, S. J. Barrow, K. Sokołowski, M. Al-Hada, N. Kornienko, M. F. Kuehnel, E. Rosta, I. Zebger, W. M. Nau, O. A. Scherman, E. Reisner, ACS Catalysis 2019, 10, 751–761, 10.1021/acscatal.9b04221
  • Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes, I. Ghosh, J. Khamrai, A. Savateev, N. Shlapakov, M. Antonietti, B. König, Science 2019, 365, 360–366, 10.1126/science.aaw3254
  • Valorization of monosaccharides towards fructopyrazines in a new sustainable and efficient eutectic medium, S. Filonenko, A. Voelkel, M. Antonietti, Green Chemistry 2019, 21, 5256–5266, 10.1039/c9gc02176k
  • One-pot photocalalytic reductive formylation of nitroarenes via multielectron transfer by carbon nitride in functional eutectic medium, Y. Markushyna, A. Völkel, A. Savateev, M. Antonietti, S. Filonenko, Journal of Catalysis 2019, 380, 186–194, 10.1016/j.jcat.2019.10.010
  • A Spectroscopic and Computationally Minimal Approach to the Analysis of Charge‐Transfer Processes in Conformationally Fluxional Mixed‐Valence and Heterobimetallic Complexes, S. Gückel, J. B. G. Gluyas, S. G. Eaves, P. Safari, D. S. Yufit, A. N. Sobolev, M. Kaupp, P. J. Low, Chemistry – A European Journal 2019, 10.1002/chem.201901200
  • Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O -Tolerant [NiFe] Hydrogenase, A. C. Schulz, S. Frielingsdorf, P. Pommerening, L. Lauterbach, G. Bistoni, F. Neese, M. Oestreich, O. Lenz, Journal of the American Chemical Society 2019, 142, 1457–1464, 10.1021/jacs.9b11506
  • Geometry of the Catalytic Active Site in [FeFe]-Hydrogenase Is Determined by Hydrogen Bonding and Proton Transfer, J. Duan, S. Mebs, K. Laun, F. Wittkamp, J. Heberle, T. Happe, E. Hofmann, U. P. Apfel, M. Winkler, M. Senger, M. Haumann, S. T. Stripp, ACS Catalysis 2019, 9, 9140–9149, 10.1021/acscatal.9b02203
  • Carbon fibre paper coated by a layered manganese oxide: a nano-structured electrocatalyst for water-oxidation with high activity over a very wide pH range, J. Melder, S. Mebs, P. A. Heizmann, R. Lang, H. Dau, P. Kurz, Journal of Materials Chemistry A 2019, 7, 25333–25346, 10.1039/c9ta08804k
  • Electromodified NiFe Alloys as Electrocatalysts for Water Oxidation: Mechanistic Implications of Time‐Resolved UV/Vis Tracking of Oxidation State Changes, S. Loos, I. Zaharieva, P. Chernev, A. Lißner, H. Dau, ChemSusChem 2019, 12, 1966–1976, 10.1002/cssc.201802737
  • Unraveling Mechanistic Reaction Pathways of the Electrochemical CO Reduction on Fe–N–C Single-Site Catalysts, W. Ju, A. Bagger, X. Wang, Y. Tsai, F. Luo, T. Möller, H. Wang, J. Rossmeisl, A. S. Varela, P. Strasser, ACS Energy Letters 2019, 4, 1663–1671, 10.1021/acsenergylett.9b01049
  • Mechanistic reaction pathways of enhanced ethylene yields during electroreduction of CO2–CO co-feeds on Cu and Cu-tandem electrocatalysts, X. Wang, J. F. de Araújo, W. Ju, A. Bagger, H. Schmies, S. Kühl, J. Rossmeisl, P. Strasser, Nature Nanotechnology 2019, 14, 1063–1070, 10.1038/s41565-019-0551-6
  • Imine‐based dynamic polymer networks as photoprogrammable amine sensing devices, M. Kathan, C. Jurissek, P. Kovaříček, S. Hecht, Journal of Polymer Science Part A: Polymer Chemistry 2019, 57, 2378–2382, 10.1002/pola.29518
  • Externe Umkehr eines Chiralitätstransfers im Photoschalter, C. Jurissek, F. Berger, F. Eisenreich, M. Kathan, S. Hecht, Angewandte Chemie 2019, 131, 1965–1969, 10.1002/ange.201812284
  • External Reversal of Chirality Transfer in Photoswitches, C. Jurissek, F. Berger, F. Eisenreich, M. Kathan, S. Hecht, Angewandte Chemie International Edition 2019, 58, 1945–1949, 10.1002/anie.201812284
  • Shining a Light on Proteolysis Targeting Chimeras, E. Teichmann, S. Hecht, ACS Central Science 2019, 5, 1645–1647, 10.1021/acscentsci.9b00955
  • Expanding the DOPA Universe with Genetically Encoded, Mussel‐Inspired Bioadhesives for Material Sciences and Medicine, N. Budisa, T. Schneider, ChemBioChem 2019, 20, 2163–2190, 10.1002/cbic.201900030
  • Anticipating alien cells with alternative genetic codes: away from the alanine world!, V. Kubyshkin, N. Budisa, Current Opinion in Biotechnology 2019, 60, 242–249, 10.1016/j.copbio.2019.05.006
  • Bilayer thickness determines the alignment of model polyproline helices in lipid membranes, V. Kubyshkin, S. L. Grage, A. S. Ulrich, N. Budisa, Physical Chemistry Chemical Physics 2019, 21, 22396–22408, 10.1039/c9cp02996f
  • Promotion of the collagen triple helix in a hydrophobic environment, V. Kubyshkin, N. Budisa, Organic & Biomolecular Chemistry 2019, 17, 2502–2507, 10.1039/c9ob00070d
  • The Alanine World Model for the Development of the Amino Acid Repertoire in Protein Biosynthesis, V. Kubyshkin, N. Budisa, International Journal of Molecular Sciences 2019, 20, 5507–0, 10.3390/ijms20215507
  • Computational Aminoacyl-tRNA Synthetase Library Design for Photocaged Tyrosine, T. Baumann, M. Hauf, F. Richter, S. Albers, A. Möglich, Z. Ignatova, N. Budisa, International Journal of Molecular Sciences 2019, 20, 2343–0, 10.3390/ijms20092343
  • In-Cell Synthesis of Bioorthogonal Alkene Tag S-Allyl-Homocysteine and Its Coupling with Reprogrammed Translation, S. Nojoumi, Y. Ma, S. Schwagerus, C. P. R. Hackenberger, N. Budisa, International Journal of Molecular Sciences 2019, 20, 2299–0, 10.3390/ijms20092299
  • Synthesis of a new metal chelating amino acid: Terpyridyl-alanine, T. Schneider, I. Gavrilova, N. Budisa, Tetrahedron Letters 2019, 60, 906–910, 10.1016/j.tetlet.2019.02.037
  • Electrochemical MIP Sensor for Butyrylcholinesterase, G. Ozcelikay, S. Kurbanoglu, X. Zhang, C. Kosak Soz, U. Wollenberger, S. A. Ozkan, A. Yarman, F. W. Scheller, Polymers 2019, 11, 1970–0, 10.3390/polym11121970
  • Electrochemical Fixation of Nitrogen and Its Coupling with Biomass Valorization with a Strongly Adsorbing and Defect Optimized Boron–Carbon–Nitrogen Catalyst, Q. Qin, T. Heil, J. Schmidt, M. Schmallegger, G. Gescheidt, M. Antonietti, M. Oschatz, ACS Applied Energy Materials 2019, 2, 8359–8365, 10.1021/acsaem.9b01852
  • Enhanced Electrocatalytic N Reduction via Partial Anion Substitution in Titanium Oxide–Carbon Composites, Q. Qin, Y. Zhao, M. Schmallegger, T. Heil, J. Schmidt, R. Walczak, G. Gescheidt‐Demner, H. Jiao, M. Oschatz, Angewandte Chemie International Edition 2019, 58, 13101–13106, 10.1002/anie.201906056
  • Operando Insight into the Correlation between the Structure and Composition of CuZn Nanoparticles and Their Selectivity for the Electrochemical CO Reduction, H. S. Jeon, J. Timoshenko, F. Scholten, I. Sinev, A. Herzog, F. T. Haase, B. Roldan Cuenya, Journal of the American Chemical Society 2019, 141, 19879–19887, 10.1021/jacs.9b10709
  • Selective CO Electroreduction to Ethylene and Multicarbon Alcohols via Electrolyte‐Driven Nanostructuring, D. Gao, I. Sinev, F. Scholten, R. M. Arán‐Ais, N. J. Divins, K. Kvashnina, J. Timoshenko, B. Roldan Cuenya, Angewandte Chemie International Edition 2019, 58, 17047–17053, 10.1002/anie.201910155
  • Operando Insights into Nanoparticle Transformations during Catalysis, A. Bergmann, B. Roldan Cuenya, ACS Catalysis 2019, 9, 10020–10043, 10.1021/acscatal.9b01831
  • Donor–acceptor covalent organic frameworks for visible light induced free radical polymerization, P. Pachfule, A. Acharjya, J. Roeser, R. P. Sivasankaran, M. Y. Ye, A. Brückner, J. Schmidt, A. Thomas, Chemical Science 2019, 10, 8316–8322, 10.1039/c9sc02601k
  • Vinylene‐Linked Covalent Organic Frameworks by Base‐Catalyzed Aldol Condensation, A. Acharjya, P. Pachfule, J. Roeser, F. Schmitt, A. Thomas, Angewandte Chemie International Edition 2019, 58, 14865–14870, 10.1002/anie.201905886
  • Silica-Templated Covalent Organic Framework-Derived Fe–N-Doped Mesoporous Carbon as Oxygen Reduction Electrocatalyst, X. Zhao, P. Pachfule, S. Li, T. Langenhahn, M. Ye, G. Tian, J. Schmidt, A. Thomas, Chemistry of Materials 2019, 31, 3274–3280, 10.1021/acs.chemmater.9b00204
  • A Polysiloxide Complex with two Chromium(III) η ‐Superoxo Moieties, M. Wind, B. Braun‐Cula, F. Schax, C. Herwig, C. Limberg, Israel Journal of Chemistry 2019, 10.1002/ijch.201900119
  • The Influence of Alkali Metal Ions on the Stability and Reactivity of Chromium(III) Superoxide Moieties Spanned by Siloxide Ligands, M. Wind, S. Hoof, C. Herwig, B. Braun‐Cula, C. Limberg, Chemistry – A European Journal 2019, 25, 5743–5750, 10.1002/chem.201900236
  • Switching from a Chromium(IV) Peroxide to a Chromium(III) Superoxide upon Coordination of a Donor in the trans Position, M. L. Wind, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg, Journal of the American Chemical Society 2019, 141, 14068–14072, 10.1021/jacs.9b06826
  • Unlocking the Spatial Control of Secondary Metabolism Uncovers Hidden Natural Product Diversity in, D. Dehm, J. Krumbholz, M. Baunach, V. Wiebach, K. Hinrichs, A. Guljamow, T. Tabuchi, H. Jenke-Kodama, R. D. Süssmuth, E. Dittmann, ACS Chemical Biology 2019, 14, 1271–1279, 10.1021/acschembio.9b00240
  • Total Synthesis of the Death Cap Toxin Phalloidin: Atropoisomer Selectivity Explained by Molecular‐Dynamics Simulations, G. Yao, J. Joswig, B. G. Keller, R. D. Süssmuth, Chemistry – A European Journal 2019, 25, 8030–8034, 10.1002/chem.201901888
  • Structural studies on tetrapyrrole containing proteins enabled by femtosecond X-ray pulses, J. Kern, F. Müh, A. Zouni in Metabolism, Structure and Function of Plant Tetrapyrroles: Control Mechanisms of Chlorophyll Biosynthesis and Analysis of Chlorophyll-Binding Proteins (Hrsg.: Bernhard Grimm), Elsevier, 2019, 33–67, ISBN: 978-0-12-819982-4
  • Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides, C. Cavedon, A. Madani, P. H. Seeberger, B. Pieber, Organic Letters 2019, 21, 5331–5334, 10.1021/acs.orglett.9b01957
  • A Phthalocyanine‐Based Layered Two‐Dimensional Conjugated Metal–Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction, H. Zhong, K. H. Ly, M. Wang, Y. Krupskaya, X. Han, J. Zhang, J. Zhang, V. Kataev, B. Büchner, I. M. Weidinger, S. Kaskel, P. Liu, M. Chen, R. Dong, X. Feng, Angewandte Chemie 2019, 131, 10787–10792, 10.1002/ange.201907002
  • Molecular Engineering of Conjugated Acetylenic Polymers for Efficient Cocatalyst‐free Photoelectrochemical Water Reduction, H. Sun, I. H. Öner, T. Wang, T. Zhang, O. Selyshchev, C. Neumann, Y. Fu, Z. Liao, S. Xu, Y. Hou, A. Turchanin, D. R. T. Zahn, E. Zschech, I. M. Weidinger, J. Zhang, X. Feng, Angewandte Chemie 2019, 131, 10476–10482, 10.1002/ange.201904978
  • Accelerated Photo‐Induced Degradation of Benzidine‐ ‐Aminothiophenolate Immobilized at Light‐Enhancing TiO Nanotube Electrodes, C. J. Querebillo, I. H. Öner, P. Hildebrandt, K. H. Ly, I. M. Weidinger, Chemistry – A European Journal 2019, 25, 16048–16053, 10.1002/chem.201902963
  • Influence of Mesityl and Thiophene Peripheral Substituents on Surface Attachment, Redox Chemistry, and ORR Activity of Molecular Iron Porphyrin Catalysts on Electrodes, R. Götz, K. H. Ly, P. Wrzolek, A. Dianat, A. Croy, G. Cuniberti, P. Hildebrandt, M. Schwalbe, I. M. Weidinger, Inorganic Chemistry 2019, 58, 10637–10647, 10.1021/acs.inorgchem.9b00043
  • Gradient metal nanoislands as a unified surface enhanced Raman scattering and surface enhanced infrared absorption platform for analytics, D. Gkogkou, T. Shaykhutdinov, C. Kratz, T. W. H. Oates, P. Hildebrandt, I. M. Weidinger, K. H. Ly, N. Esser, K. Hinrichs, The Analyst 2019, 144, 5271–5276, 10.1039/C9an00839J
  • Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions, Q. Wu, A. Roy, E. Irran, Z. Qu, S. Grimme, H. F. T. Klare, M. Oestreich, Angewandte Chemie International Edition 2019, 58, 17307–17311, 10.1002/anie.201911282
  • General Synthesis and Optical Properties of -Aryl- ′-Silyldiazenes, C. Chauvier, L. Finck, S. Hecht, M. Oestreich, Organometallics 2019, 38, 4679–4686, 10.1021/acs.organomet.9b00654
  • Three-Dimensional Bioelectrodes Utilizing Graphene Based Bioink, R. M. L. Werchmeister, J. Tang, X. Xiao, U. Wollenberger, H. A. Hjuler, J. Ulstrup, J. Zhang, Journal of The Electrochemical Society 2019, 166, 10.1149/2.0261916jes
  • Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates, J. A. Birrell, V. Pelmenschikov, N. Mishra, H. Wang, Y. Yoda, K. Tamasaku, T. B. Rauchfuss, S. P. Cramer, W. Lubitz, S. DeBeer, Journal of the American Chemical Society 2019, 142, 222–232, 10.1021/jacs.9b09745
  • X‐ray Crystallography and Vibrational Spectroscopy Reveal the Key Determinants of Biocatalytic Dihydrogen Cycling by [NiFe] Hydrogenases, Y. Ilina, C. Lorent, S. Katz, J. Jeoung, S. Shima, M. Horch, I. Zebger, H. Dobbek, Angewandte Chemie International Edition 2019, 58, 18710–18714, 10.1002/anie.201908258
  • Discriminating changes in intracellular NADH/NAD+ levels due to anoxicity and H2 supply in R. eutropha cells using the Frex fluorescence sensor, S. Wilkening, F. J. Schmitt, O. Lenz, I. Zebger, M. Horch, T. Friedrich, Biochimica et Biophysica Acta (BBA) - Bioenergetics 2019, 1860, 148062–0, 10.1016/j.bbabio.2019.148062
  • Understanding the structure and dynamics of hydrogenases by ultrafast and two-dimensional infrared spectroscopy, M. Horch, J. Schoknecht, S. L. D. Wrathall, G. M. Greetham, O. Lenz, N. T. Hunt, Chemical Science 2019, 10, 8981–8989, 10.1039/C9SC02851J
  • Synthesis of -heterocycles from diamines H -driven NADPH recycling in the presence of O, A. Al-Shameri, N. Borlinghaus, L. Weinmann, P. N. Scheller, B. M. Nestl, L. Lauterbach, Green Chemistry 2019, 21, 1396–1400, 10.1039/C8GC03798A
  • How [FeFe]-Hydrogenase Facilitates Bidirectional Proton Transfer, M. Senger, V. Eichmann, K. Laun, J. Duan, F. Wittkamp, G. Knör, U. P. Apfel, T. Happe, M. Winkler, J. Heberle, S. T. Stripp, Journal of the American Chemical Society 2019, 141, 17394–17403, 10.1021/jacs.9b09225
  • Investigating the Structure and Dynamics of Apo‐Photosystem II, R. Han, K. Rempfer, M. Zhang, H. Dobbek, A. Zouni, H. Dau, S. Luber, ChemCatChem 2019, 11, 4072–4080, 10.1002/cctc.201900351
  • Asymmetry in the Ligand Coordination Sphere of the [FeFe] Hydrogenase Active Site Is Reflected in the Magnetic Spin Interactions of the Aza-propanedithiolate Ligand, E. J. Reijerse, V. Pelmenschikov, J. A. Birrell, C. P. Richers, M. Kaupp, T. B. Rauchfuss, S. P. Cramer, W. Lubitz, The Journal of Physical Chemistry Letters 2019, 10, 6794–6799, 10.1021/acs.jpclett.9b02354
  • Insights from Te and Fe nuclear resonance vibrational spectroscopy: a [4Fe–4Te] cluster from two points of view, F. Wittkamp, N. Mishra, H. Wang, H. C. Wille, R. Steinbrügge, M. Kaupp, S. P. Cramer, U. P. Apfel, V. Pelmenschikov, Chemical Science 2019, 10, 7535–7541, 10.1039/c9sc02025j
  • Site‐Resolved Observation of Vibrational Energy Transfer Using a Genetically Encoded Ultrafast Heater, T. Baumann, M. Hauf, F. Schildhauer, K. B. Eberl, P. M. Durkin, E. Deniz, J. G. Löffler, C. G. Acevedo‐Rocha, J. Jaric, B. M. Martins, H. Dobbek, J. Bredenbeck, N. Budisa, Angewandte Chemie International Edition 2019, 58, 2899–2903, 10.1002/anie.201812995
  • Design of a light-gated proton channel based on the crystal structure of rhodopsin, R. Fudim, M. Szczepek, J. Vierock, A. Vogt, A. Schmidt, G. Kleinau, P. Fischer, F. Bartl, P. Scheerer, P. Hegemann, Science Signaling 2019, 12, 10.1126/scisignal.aav4203
  • Macro/Microporous Covalent Organic Frameworks for Efficient Electrocatalysis, X. Zhao, P. Pachfule, S. Li, T. Langenhahn, M. Ye, C. Schlesiger, S. Praetz, J. Schmidt, A. Thomas, Journal of the American Chemical Society 2019, 141, 6623–6630, 10.1021/jacs.9b01226