Publications 2020

  • Enhancing tris(pyrazolyl)borate‐based models of cysteine/cysteamine dioxygenases via the sterics – increased reactivities, full product characterization and hints to initial superoxide formation, C. Limberg, L. Müller, S. Hoof, M. Keck, C. Herwig, Chemistry – A European Journal 2020, 10.1002/chem.202001818
  • Routes to Heterotrinuclear Metal Siloxide Complexes for Cooperative Activation of O, M. L. Wind, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg, Inorganic Chemistry 2020, 10, 6866–6875, 10.1021/acs.inorgchem.0c00279
  • In-cell architecture of an actively transcribing-translating expressome, F. J. O’Reilly, L. Xue, A. Graziadei, L. Sinn, S. Lenz, D. Tegunov, C. Blötz, N. Singh, W. J. H. Hagen, P. Cramer, J. Stülke, J. Mahamid, J. Rappsilber, Science 2020, 6503, 554–557, 10.1126/science.abb3758
  • Cryo-EM structures of holo condensin reveal a subunit flip-flop mechanism, B. G. Lee, F. Merkel, M. Allegretti, M. Hassler, C. Cawood, L. Lecomte, F. J. O’Reilly, L. R. Sinn, P. Gutierrez-Escribano, M. Kschonsak, S. Bravo, T. Nakane, J. Rappsilber, L. Aragon, M. Beck, J. Löwe, C. H. Haering, Nature structural & molecular biology 2020, 10.1038/s41594-020-0457-x
  • Assessment of the manganese cluster’s oxidation state via photoactivation of photosystem II microcrystals, M. H. Cheah, M. Zhang, D. Shevela, F. Mamedov, A. Zouni, J. Messinger, Proceedings of the National Academy of Sciences 2020, 1, 141–145, 10.1073/pnas.1915879117
  • Untangling the sequence of events during the S → S transition in photosystem II and implications for the water oxidation mechanism, M. Ibrahim, T. Fransson, R. Chatterjee, M. H. Cheah, R. Hussein, L. Lassalle, K. D. Sutherlin, I. D. Young, F. D. Fuller, S. Gul, I. S. Kim, P. S. Simon, C. de Lichtenberg, P. Chernev, I. Bogacz, C. C. Pham, A. M. Orville, N. Saichek, T. Northen, A. Batyuk, S. Carbajo, R. Alonso-Mori, K. Tono, S. Owada, A. Bhowmick, R. Bolotovsky, D. Mendez, N. W. Moriarty, J. M. Holton, H. Dobbek, A. S. Brewster, P. D. Adams, N. K. Sauter, U. Bergmann, A. Zouni, J. Messinger, J. Kern, V. K. Yachandra, J. Yano, Proceedings of the National Academy of Sciences 2020, 23, 12624–12635, 10.1073/pnas.2000529117
  • Structural basis of light‐harvesting in the photosystem II core complex, F. Müh, A. Zouni, Protein Science 2020, 5, 1090–1119, 10.1002/pro.3841
  • Counter-Intuitive Gas-phase Reactivities of [V ] and [V O] towards CO Reduction: Insight from Electronic Structure Calculations, J. Li, C. Geng, T. Weiske, H. Schwarz, Angewandte Chemie International Edition 2020, 59, 12308–12314, 10.1002/anie.202001223
  • Overcoming limitations in dual photoredox/nickel-catalysed C–N cross-couplings due to catalyst deactivation, S. Gisbertz, S. Reischauer, B. Pieber, Nature Catalysis 2020, 10.1038/s41929-020-0473-6
  • Heterogeneous photocatalysis in organic synthesis, S. Gisbertz, B. Pieber, ChemPhotoChem 2020, 10.1002/cptc.202000014
  • Evidence for Photocatalyst Involvement in Oxidative Additions of Nickel-Catalyzed Carboxylate -Arylations, J. A. Malik, A. Madani, B. Pieber, P. H. Seeberger, Journal of the American Chemical Society 2020, 25, 11042–11049, 10.1021/jacs.0c02848
  • An oscillatory plug flow photoreactor facilitates semi-heterogeneous dual nickel/carbon nitride photocatalytic C–N couplings, C. Rosso, S. Gisbertz, J. D. Williams, H. P. L. Gemoets, W. Debrouwer, B. Pieber, C. O. Kappe, Reaction Chemistry & Engineering 2020, 3, 597–604, 10.1039/d0re00036a
  • Synergistic electroreduction of carbon dioxide to carbon monoxide on bimetallic layered conjugated metal-organic frameworks, H. Zhong, M. Ghorbani-Asl, K. H. Ly, J. Zhang, J. Ge, M. Wang, Z. Liao, D. Makarov, E. Zschech, E. Brunner, I. M. Weidinger, J. Zhang, A. V. Krasheninnikov, S. Kaskel, R. Dong, X. Feng, Nature Communications 2020, 11, 1–10, 10.1038/s41467-020-15141-y
  • Spectroscopic investigations under whole-cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase, L. S. Mészáros, P. Ceccaldi, M. Lorenzi, H. J. Redman, E. Pfitzner, J. Heberle, M. Senger, S. T. Stripp, G. Berggren, Chemical Science 2020, 11, 4608–4617, 10.1039/D0SC00512F
  • Cobalt‐Exchanged Poly(Heptazine Imides) as Transition Metal–N Electrocatalysts for the Oxygen Evolution Reaction, M. Ye, S. Li, X. Zhao, N. V. Tarakina, C. Teutloff, W. Y. Chow, R. Bittl, A. Thomas, Advanced Materials 2020, 9, 1903942–0, 10.1002/adma.201903942
  • Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes, A. Roy, V. Bonetti, G. Wang, Q. Wu, H. F. T. Klare, M. Oestreich, Organic Letters 2020, 3, 1213–1216, 10.1021/acs.orglett.0c00173
  • Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion, Q. Wu, A. Roy, G. Wang, E. Irran, H. F. T. Klare, M. Oestreich, Angewandte Chemie International Edition 2020, 26, 10523–10526, 10.1002/anie.202003799
  • Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration, T. He, G. Wang, V. Bonetti, H. F. T. Klare, M. Oestreich, Angewandte Chemie International Edition 2020, 10.1002/anie.202004320
  • Electrochemical Biosensors Employing Natural and Artificial Heme Peroxidases on Semiconductors, B. Neumann, U. Wollenberger, Sensors 2020, 13, 3692–3714, 10.3390/s20133692
  • Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis, L. B. Gee, V. Pelmenschikov, H. Wang, N. Mishra, Y. C. Liu, Y. Yoda, K. Tamasaku, M. H. Chiang, S. P. Cramer, Chemical Science 2020, 21, 5487–5493, 10.1039/D0SC01290D
  • The structure of human thyroglobulin, F. Coscia, A. Taler-Verčič, V. T. Chang, L. Sinn, F. J. O’Reilly, T. Izoré, M. Renko, I. Berger, J. Rappsilber, D. Turk, J. Löwe, Nature 2020, 578, 627–630, 10.1038/s41586-020-1995-4
  • On the Crucial Role of Isolated Electronic States in the Thermal Reaction of ReC with Dihydrogen, J. Li, C. Geng, T. Weiske, H. Schwarz, Angewandte Chemie International Edition 2020, 24, 9370–9376, 10.1002/anie.202001599
  • Shedding Light on Proton and Electron Dynamics in [FeFe] Hydrogenases, C. Lorent, S. Katz, J. Duan, C. J. Kulka, G. Caserta, C. Teutloff, S. Yadav, U. P. Apfel, M. Winkler, T. Happe, M. Horch, I. Zebger, Journal of the American Chemical Society 2020, 12, 5493–5497, 10.1021/jacs.9b13075

Publications 2019

  • A Polysiloxide Complex with two Chromium(III) η ‐Superoxo Moieties, M. Wind, B. Braun‐Cula, F. Schax, C. Herwig, C. Limberg, Israel Journal of Chemistry 2019, 10.1002/ijch.201900119
  • The Influence of Alkali Metal Ions on the Stability and Reactivity of Chromium(III) Superoxide Moieties Spanned by Siloxide Ligands, M. Wind, S. Hoof, C. Herwig, B. Braun‐Cula, C. Limberg, Chemistry – A European Journal 2019, 22, 5743–5750, 10.1002/chem.201900236
  • Switching from a Chromium(IV) Peroxide to a Chromium(III) Superoxide upon Coordination of a Donor in the trans Position, M. L. Wind, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg, Journal of the American Chemical Society 2019, 36, 14068–14072, 10.1021/jacs.9b06826
  • Unlocking the Spatial Control of Secondary Metabolism Uncovers Hidden Natural Product Diversity in, D. Dehm, J. Krumbholz, M. Baunach, V. Wiebach, K. Hinrichs, A. Guljamow, T. Tabuchi, H. Jenke-Kodama, R. D. Süssmuth, E. Dittmann, ACS Chemical Biology 2019, 6, 1271–1279, 10.1021/acschembio.9b00240
  • Total Synthesis of the Death Cap Toxin Phalloidin: Atropoisomer Selectivity Explained by Molecular‐Dynamics Simulations, G. Yao, J. Joswig, B. G. Keller, R. D. Süssmuth, Chemistry – A European Journal 2019, 34, 8030–8034, 10.1002/chem.201901888
  • Structural studies on tetrapyrrole containing proteins enabled by femtosecond X-ray pulses, J. Kern, F. Müh, A. Zouni in Metabolism, Structure and Function of Plant Tetrapyrroles: Control Mechanisms of Chlorophyll Biosynthesis and Analysis of Chlorophyll-Binding Proteins (Hrsg.: Bernhard Grimm), Elsevier, 2019, 33–67, ISBN: 978-0-12-819982-4
  • Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides, C. Cavedon, A. Madani, P. H. Seeberger, B. Pieber, Organic Letters 2019, 13, 5331–5334, 10.1021/acs.orglett.9b01957
  • A Phthalocyanine‐Based Layered Two‐Dimensional Conjugated Metal–Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction, H. Zhong, K. H. Ly, M. Wang, Y. Krupskaya, X. Han, J. Zhang, J. Zhang, V. Kataev, B. Büchner, I. M. Weidinger, S. Kaskel, P. Liu, M. Chen, R. Dong, X. Feng, Angewandte Chemie 2019, 131, 10787–10792, 10.1002/ange.201907002
  • Molecular Engineering of Conjugated Acetylenic Polymers for Efficient Cocatalyst‐free Photoelectrochemical Water Reduction, H. Sun, I. H. Öner, T. Wang, T. Zhang, O. Selyshchev, C. Neumann, Y. Fu, Z. Liao, S. Xu, Y. Hou, A. Turchanin, D. R. T. Zahn, E. Zschech, I. M. Weidinger, J. Zhang, X. Feng, Angewandte Chemie 2019, 30, 10476–10482, 10.1002/ange.201904978
  • Accelerated Photo‐Induced Degradation of Benzidine‐ ‐Aminothiophenolate Immobilized at Light‐Enhancing TiO Nanotube Electrodes, C. J. Querebillo, I. H. Öner, P. Hildebrandt, K. H. Ly, I. M. Weidinger, Chemistry – A European Journal 2019, 70, 16048–16053, 10.1002/chem.201902963
  • Influence of Mesityl and Thiophene Peripheral Substituents on Surface Attachment, Redox Chemistry, and ORR Activity of Molecular Iron Porphyrin Catalysts on Electrodes, R. Götz, K. H. Ly, P. Wrzolek, A. Dianat, A. Croy, G. Cuniberti, P. Hildebrandt, M. Schwalbe, I. M. Weidinger, Inorganic Chemistry 2019, 16, 10637–10647, 10.1021/acs.inorgchem.9b00043
  • Gradient metal nanoislands as a unified surface enhanced Raman scattering and surface enhanced infrared absorption platform for analytics, D. Gkogkou, T. Shaykhutdinov, C. Kratz, T. W. H. Oates, P. Hildebrandt, I. M. Weidinger, K. H. Ly, N. Esser, K. Hinrichs, The Analyst 2019, 17, 5271–5276, 10.1039/C9an00839J
  • Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions, Q. Wu, A. Roy, E. Irran, Z. Qu, S. Grimme, H. F. T. Klare, M. Oestreich, Angewandte Chemie International Edition 2019, 48, 17307–17311, 10.1002/anie.201911282
  • General Synthesis and Optical Properties of -Aryl- ′-Silyldiazenes, C. Chauvier, L. Finck, S. Hecht, M. Oestreich, Organometallics 2019, 24, 4679–4686, 10.1021/acs.organomet.9b00654
  • Three-Dimensional Bioelectrodes Utilizing Graphene Based Bioink, R. M. L. Werchmeister, J. Tang, X. Xiao, U. Wollenberger, H. A. Hjuler, J. Ulstrup, J. Zhang, Journal of the Electrochemical Society 2019, 166, 170–177, 10.1149/2.0261916jes
  • Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates, J. A. Birrell, V. Pelmenschikov, N. Mishra, H. Wang, Y. Yoda, K. Tamasaku, T. B. Rauchfuss, S. P. Cramer, W. Lubitz, S. DeBeer, Journal of the American Chemical Society 2019, 1, 222–232, 10.1021/jacs.9b09745
  • X‐ray Crystallography and Vibrational Spectroscopy Reveal the Key Determinants of Biocatalytic Dihydrogen Cycling by [NiFe] Hydrogenases, Y. Ilina, C. Lorent, S. Katz, J. Jeoung, S. Shima, M. Horch, I. Zebger, H. Dobbek, Angewandte Chemie International Edition 2019, 51, 18710–18714, 10.1002/anie.201908258
  • How [FeFe]-Hydrogenase Facilitates Bidirectional Proton Transfer, M. Senger, V. Eichmann, K. Laun, J. Duan, F. Wittkamp, G. Knör, U. P. Apfel, T. Happe, M. Winkler, J. Heberle, S. T. Stripp, Journal of the American Chemical Society 2019, 43, 17394–17403, 10.1021/jacs.9b09225
  • Site‐Resolved Observation of Vibrational Energy Transfer Using a Genetically Encoded Ultrafast Heater, T. Baumann, M. Hauf, F. Schildhauer, K. B. Eberl, P. M. Durkin, E. Deniz, J. G. Löffler, C. G. Acevedo‐Rocha, J. Jaric, B. M. Martins, H. Dobbek, J. Bredenbeck, N. Budisa, Angewandte Chemie International Edition 2019, 9, 2899–2903, 10.1002/anie.201812995
  • Design of a light-gated proton channel based on the crystal structure of rhodopsin, R. Fudim, M. Szczepek, J. Vierock, A. Vogt, A. Schmidt, G. Kleinau, P. Fischer, F. Bartl, P. Scheerer, P. Hegemann, Science Signaling 2019, 573, 10.1126/scisignal.aav4203
  • Macro/Microporous Covalent Organic Frameworks for Efficient Electrocatalysis, X. Zhao, P. Pachfule, S. Li, T. Langenhahn, M. Ye, C. Schlesiger, S. Praetz, J. Schmidt, A. Thomas, Journal of the American Chemical Society 2019, 16, 6623–6630, 10.1021/jacs.9b01226

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Unifying Systems in Catalysis (UniSysCat) is funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany´s Excellence Strategy – EXC 2008/1– 390540038